Agreed. In theory it could pull off but as stated it would need to be quick and accurate but if they responded quickly they could pull it off. They off course would need to be well disciplined. Now I believe that Uruks are a more disciplined fighting unit than regular orcs so with those it could be possible, however with just orcs I don't see the strict regiment to accomplish the feat.
I don't think it's a sure fire method to halt the attack but yes if all those conditions were met than I could say that it could be rather effective to fire a catapult into the chargers.
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“I wish it need not have happened in my time," said Frodo.
"So do I," said Gandalf, "and so do all who live to see such times. But that is not for them to decide. All we have to decide is what to do with the time that is given us.”
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