Among the Children of Eru, Luthien sits at the top of the list:
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Originally Posted by Of Beren and Luthien, Silmarillion
Then all memory of his pain departed from him, and he fell into an enchantment; for Luthien was the most beautiful of all the Children of Iluvatar.
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As for Varda, we know that:
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Originally Posted by Valaquenta, Silmarillion
Too great is her beauty to be declared in the words of Men or of Elves; for the light of Iluvatar lives still in her face.
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Given the status of the valar, I would personally go with Varda.