Jumping in feet first here, I apologize.
Some how I can't see the insular hobbits finding out about foreign coffee. But I did a bit of Googling and found that New South Wales, Australia is a coffee growing area. Now New South Wales has a highest maximum temperature of 50.0C (122.0F), Wilcannia, 11 January 1939 and lowest minimum temperature of -23.0C (-9.4F), Charlotte Pass, 29 June 1994. It would seem that if they could grow the stuff there, the Shire might also have a bit of it as well, perhaps as delicacy growing in a sheltered spot and defended against frost and snow with fire pots and tarps. In anycase, I imagine that it would have to be replanted frequently.
Roasting the stuff would not be an amazing discovery, as many spices are roasted to facilitate grinding them. And then again, did Tolkien actually mention that the concoction produced was as good as the stuff we have from now warmer climes? It might have and entirely different character. Or different base. Besides chicory, toasted beets, acorns, rye, field peas and okra seed have all been used as coffee substitutes.
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