Great game! I'm still wondering how my name ended up on that list.
Well, I'm on GMT+1, but I'm already used to being forced to cast an early vote. I suppose 2 AM would work best for me, but any time is fine. Though, like Estelyn, 12AM or 1AM would force me to vote extremely early, since I'm physically unable to get up before 7 in the morning.
As for professions, I will be a merchant selling love potions. Can't guarantee they'll work, though.