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No matter which doom Arwen chose, biologically, she was an elf.
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As stated above, biologically she was *not* an elf. She was in no way an elf really, other than having a similar course of aging until she was forced to decide. The original decree was that any being with any amount of blood was mortal. A decision to be immortal would've been the departure from how things had "naturally" occurred before - not a decision to be mortal.