It seemed like Frodo got stung on the right collarbone, or somewhere close to the right collarbone. When you see Frodo's mithril shirt in Moria, you see that the shirt doesn't completely cover his collarbones. By pure chance, Shelob's stinger might have gotten through there.
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But Melkor also was there, and he came to the house of Fëanor, and there he slew Finwë King of the Noldor before his doors, and spilled the first blood in the Blessed Realm; for Finwë alone had not fled from the horror of the Dark.
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